Product ID:GENETRON 113 TRICHLOROTRIFLUOROETHANE
MSDS Date:02/01/1987
FSC:6850
NIIN:00-033-8851
MSDS Number: BCVTC

ALLIED CORP., ALLIED CHEMICAL,CSS DEPT.

COLUMBIA RD & PARK AVE
MORRISTOWN, NJ 07960
US

Emergency Phone: 201-455-2000

Info Phone: 201-455-2000

Cage: JO859

ALLIED-SIGNAL CORP ENGINEERED MATERIALS DIV

MORRISTOWN, NJ 07960 US

Telephone: 201-455-2000

Cage: 40991

1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE (FREON 113) (SARA

CAS: 76-13-1

RTECS: KJ4000000

OSHA PEL 1000PPM/1250STEL

ACGIH TLV: 1000PPM/1250STEL9192

METHYL CHLOROFORM (1,1,1-TRICHLOROEHANE) (SARA III)

CAS: 71-55-6

RTECS: KJ2975000

Fraction By Weight: 1%

OSHA PEL 350 PPM/450 STEL

ACGIH TLV: 350 PPM/450STEL;9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

OTHER CHLORINATED SOLVENTS

Fraction By Weight: 1%

OTHER CHEMICALS

Fraction By Weight: BALANCE

LD50 LC50 Mixture:LD50 (ORAL RAT) IS 43,000 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE-EYE:MAY CAUSE MILD IRRITATION &
CONJUNCTIVITIS.SKIN:IRRITATION.EXCESSIVE CONTACT MAY CAUSE
DEFATTING.INHALATION:AT LOW LEVELS CAN CAUSE DROWSINESS,LOSS OF
CONCENTRATION,"HEAVINESS"IN HEAD.AT HIG H CONCENTRATION,CARDIAC
EFFECTS.INGESTION:MAY CAUSE DISCOMFORT & SYMPTOMS SIMILAR TO
INHALATION.CHRONIC-LOW TOXICITY-RAT
Effects of Overexposure:SEE HEALTH HAZARDS SECTION.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:GET MEDICAL ATTENTION-EYE:FLUSH W/WATER 15 MIN,HOLD LIDS
OPEN.SKIN:FLUSH WITH WATER.INHALED:REMOVE TO FRESH AIR.GIVE
CPR/OXYGEN IF NECESSARY.DON'T GIVE STIMULANTS.EPINEPHRINE MAY
ADVERSELY AFFECT THE HEART WITH FATAL RESULTS.IF SWALLOWED:IF
CONSCIOUS,INDUCE VOMITING.

Flash Point:NONFLAMMABLE
Extinguishing Media:NON FLAMMABLE.USE WATER FOG,CARBON DIOXIDE/DRY
CHEMICAL FOR SURROUNDING FIRE.USE WATER TO COOL FIRE-EXPOSED
CONTAINERS.
Fire Fighting Procedures:WEAR NIOSH-APPROVED SELF CONTAINED BREATHING
APPARATUS WITH A FULL FACEPIECE OPERATED IN THE POSITIVE PRESSURE
DEMAND MODE WHEN FIGHTING FIRES.
Unusual Fire/Explosion Hazard:SEE HAZARDOUS DECOMPOSITION PRODUCT
SECTION.

Spill Release Procedures:REMOVE ANY FLAMES & SHUT OFF LEAK IF WITHOUT
RISK.WEAR PROTECTIVE EQUIPMENTS.ABSORB SMALL SPILL ON
PAPER,VERMICULITE.LARGE SPILLS:DIKE AREA.PUMP LIQUID TO SALVAGE
TANK.TAKE UP THE REST BY SAND/CLAY & SHOVEL TO A CONTAINER.PUMP
SHOULD NOT GET TOO HOT.
Neutralizing Agent:NONE GIVEN

Handling and Storage Precautions:STORE CONTAINERS TIGHTLY CLOSED IN A
COOL,WELL VENTILATED PLACE,AWAY FROM HEAT & FLAMES.EMPTY CONTAINER
MAY CONTAIN HAZARDOUS RESIDUES.
Other Precautions:OBSERVE ALL LABELED HAZARD PRECAUTIONS.CLOSURES
SHOULD BE REMOVED CAREFULLY TO RELIEVE POSSIBLE INTERNAL PRESSURE
AND,WHEN EMPTY,TO AVOID ACCIDENTAL EXPOSURE TO ANY ENTRAPPED
VAPORS.INSPECT AIR-CONDIT IONING SYSTEMS FOR CORROSION.

Respiratory Protection:IF WORKPLACE EXPOSURE LIMIT OF PRODUCT EXCEEDS
THE TLV, A NIOSH/MSHA APPROVED AIR SUPPLIED RESPIRATOR OR A
SELF-CONTAINED BREATHING APPARATUS IS ADVISED.
Ventilation:MECHANICAL (GENERAL AND/OR LOCAL EXHAUST) VENTILATION.
Protective Gloves:PVA
Eye Protection:CHEMICAL SPLASH GOGGLES
Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER.
INDUSTRIAL-TYPE WORK CLOTHING AND APRON AS REQUIRED.
Work Hygienic Practices:DO NOT INHALE VAPORS. WASH HANDS BEFORE EATING
AND DRINKING.
Supplemental Safety and Health

HCC:N1
Boiling Pt:B.P. Text:118F,48C
Melt/Freeze Pt:M.P/F.P Text:-31F,-35C
Decomp Temp:Decomp Text:482F,250C
Vapor Pres:290
Vapor Density:6.5
Spec Gravity:1.57
Evaporation Rate & Reference:1.3 (ETHER = 1)
Solubility in Water:0.035 %
Appearance and Odor:COLORLESS LIQUID WITH FAINT ETHEREAL ODOR
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
POWDERED ALUMINUM,FINELY DIVIDED BARIUM,LITHIUM SHAVINGS,POWDER
TITANIUM,ZINC,BERYLLIUM & MAGNESIUM.ALLOYS WITH >2% MG.
Stability Condition to Avoid:TEMPERATURES >250C, LIGHTED CIGARETTES
OPEN FLAMES, HOT SPOTS, WELDING
Hazardous Decomposition Products:HYDROGEN FLUORIDE AND CHLORIDE,
CARBONYL HALIDES, SUCH AS PHOSGENE

Waste Disposal Methods:CONSULT FEDERAL, STATE AND LOCAL AUTHORITIES FOR
PROPER DISPOSAL PROCEDURES.

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This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.